Question: What is this famous water you want to replicate?
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Source Ca Mg Na SO4 Cl HCO3
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Promash 268 62 30 638 36 141
Noonan 275 15 25 450 30 260
Daniels 294 24 24 801 36 0
Palmer 352 24 44 820 16 320
And that's just the books on my shelf. You see that sulfate content ranges from 450-820, and bicarbonate from 0 to 320. So, it's not clear at all which water you should be emulating. Compare this to what I have listed for our part of St. Louis:
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Ca Mg Na SO4 Cl HCO3
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21 15 29 41 20 110
In terms of flavor, the big thing going on consistently is the elevated sulfate content. I would just start with tap water (you do want all the other minerals there in trace amounts), and add some gypsum (Calcium Sulfate). I did 3g into the mash on the last bitter I brewed; I just calculated out that this should have given me something like 100 ppm SO4 in the finished product. My back of the envelope calculations say that on my system, 5g gypsum will elevate sulfate levels by 100 ppm in the finished product. I would start there.
Keep in mind that many authors say what is relevant is the sulfate to chloride ratio; you see above that this ranges from 15:1 (Noonan) to 50:1 (Palmer). My typical gypsum addition of 3g puts it at more like 5:1.
If you want to taste what 3g gypsum does to a Bitter, I have it on tap right now
